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| β-二酮双核铜(Ⅰ)配合物的合成与结构 | |
| 引用本文： | 杨瑞娜,王冬梅,李彩云,刘应凡,金斗满. β-二酮双核铜(Ⅰ)配合物的合成与结构[J]. 无机化学学报, 2001, 17(2): 209-214 |
| 作者姓名： | 杨瑞娜 王冬梅 李彩云 刘应凡 金斗满 |
| 作者单位： | 1. 河南化学研究所；南京大学 2. 河南化学研究所, 3. 平原大学, 4. 南京大学 |
| 基金项目： | 国家自然科学基金资助项目(No-29871009)和河南省杰出青年及自然科学基金资助项目。 |
| 摘 要： | 室温下，通过双二苯基膦甲烷还原[Cu(tfac) |
| 关 键 词： | 双核配合物 β－二酮 还原结构 铜 合成 双二苯基膦甲烷 |
| 收稿时间： | 2000-08-17 |
| 修稿时间： | 2000-08-17 |
Synthesis and Structure ofBinuclear Copper ( |
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| YANG Rui-N,WANG Dong-Mei,LI Cai-Yun,LIU Ying-Fan and JIN Dou-Man. Synthesis and Structure ofBinuclear Copper ([J]. Chinese Journal of Inorganic Chemistry, 2001, 17(2): 209-214 | |
| Authors: | YANG Rui-N WANG Dong-Mei LI Cai-Yun LIU Ying-Fan JIN Dou-Man |
| Affiliation: | Henan Institute of Chemistry, Zhengzhou 450002;State Key lab of Coordination Chemistry, Nanjing University, Nanjing 210093,Henan Institute of Chemistry, Zhengzhou 450002,Pingyuan University, Xinxiang 475300,Henan Institute of Chemistry, Zhengzhou 450002 and State Key lab of Coordination Chemistry, Nanjing University, Nanjing 210093 |
| Abstract: | At room temperature, the binuclear copper (Ⅰ) complex [Cu(dppm) (tfac)]2(1) [dppm=bis (diphenylphosphine) methane, tfac = 2-thenoyltrifluoroacetone] was prepared by reduction reaction between dppm and Cu(tfac)2. The structure of the complex was characterized by IR,31P NMR, XPS spectra and X-ray diffraction analysis. Crystal(1) belongs to monoclinic, space group P21/n,a=1.3028(5), b=1.3744(4), c=2.0278(5) nm, 3=94.48(2)°, Dc=1.351g·cm-3, Z=2, V=3.6199nm3, R=0.04978. Each copper (Ⅱ) ion is coordinated by the phosphorus of dppm and two oxygen atoms of tfac to form tetrahedron coordination structure. |
| Keywords: | copper complex reduction crystal structure |
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