MoS2 nanorods with inner caves through synchronous encapsulation of sulfur for high performance Li–S cathodes |
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作者姓名: | Yikun Yi Zechen Liu Pu Yang Tao Wang Xuewen Zhao Hongyang Huang Yonghong Cheng Jinying Zhang Mingtao Li |
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作者单位: | Shaanxi Key Laboratory of Energy Chemical Process Intensification;State Key Laboratory of Electrical Insulation and Power Equipment;Guangdong Xi’an Jiaotong University Academy;School of Environment and Architecture |
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基金项目: | supported by the National Natural Science Foundation of China(No.21771143);Natural Science Foundation of Shaanxi Province(grant no.2017ZDJC-30,2018JQ2027);Key Research Project of Shaanxi Province(2018ZDCXLGY-08-06);Natural Science Foundation of Jiangsu Province(grant no.BK20170413);Fundamental Research Funds for the Central Universities(grant no.xjj2017084);Foshan Science and Technology Bureau Project(No.2017AG100443);supported by the Cyrus Tang Foundation through the Tang Scholar Program。 |
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摘 要: | Lithium–sulfur(Li–S)batteries have become one of the most promising candidates for next-generation batteries owing to their high specific capacity,low cost,and environment-friendliness.Many efforts have been made to mitigate the"shuttle effect"through physical adsorption and chemical bonding.MoS2 has been proposed as a cathode material to provide effective anchoring sites for lithium polysulfides(Li PSs),but is still limited by its layer structure.Herein,we designed novel MoS2 nanorods with inner caves based on our previous work,and performed synchronous encapsulation of sulfur during the synthesis process.The outer MoS2 tubular shells physically inhibit the outward diffusion of polysulfide species while the inner particles chemically anchor the polysulfides to prevent shuttling.As the cathode matrix in Li–S batteries,the electrochemical results deliver a high initial discharge capacity of 1213 mAhg^-1 for sulfur at 0.1 C.After cycling at 1 C for 300 cycles,the cells exhibit a capacity decay of only 0.076%per cycle and high average coulombic efficiency over 95%.The tubular MoS2 structure is an innovative and appealing design,which could be regarded as a prospective substrate for the improved performance of Li–S batteries.
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关 键 词: | MOS2 nanorod INNER caves SYNCHRONOUS ENCAPSULATION of SULFUR Cathode matrix |
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