Catalytic effect of hydroxy groups on reaction of polyamine with tert-butyl acrylate |
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| Authors: | J ?vachula and J Horálek |
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| Institution: | (1) Institute of Chemical Technology, 532 10 Pardubice,  SFR;(2) Research Institute of Synthetic Resins and Lacquers, 532 07 Pardubice, SFR |
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| Abstract: | The reaction of N-cyclohexyl-1,3-propanediamine with tert-butyl acrylate and the catalytic effect of hydroxy groups on the reaction course was investigated by Near Infrared spectroscopy. The reaction was found to be bimolecular and of second order. The dependence of rate constant on catalyst concentration (diols) is linear and the structure of diol used has no effect.
             N- -1,3-    -  .             .   .  () , .
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