| 气—固相置换法合成杂原子磷酸盐分子筛及其性能研究 |
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| 引用本文： | 左丽华,庞文琴,裘式纶,孟宪平,陈克增.气—固相置换法合成杂原子磷酸盐分子筛及其性能研究[J].无机化学学报,1988,4(2):74-81. |
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| 作者姓名： | 左丽华 庞文琴 裘式纶 孟宪平 陈克增 |
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| 作者单位： | 吉林大学合成与催化研究所，吉林大学合成与催化研究所，吉林大学合成与催化研究所，吉林大学合成与催化研究所，吉林大学合成与催化研究所 北京九一四信箱基础部 |
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| 摘 要： | 用气—固相置换法合成SAPO—5,TAPO—5,BAPO—5分子筛。通过顺磁共振波谱,X射线光电子能谱,固体高分辨魔角核磁共振谱,红外酸性及晶胞参数等的测定多种研究方法,为杂原子Ti,Si,B进入分子筛骨架提供了证据。考察了分子筛的热稳定性,吸附性和晶体形貌。
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| 关 键 词： | 气-固相置换法 杂原子 磷酸盐分子筛 |
| 收稿时间： | 3/9/1987 12:00:00 AM |
STUDY ON VAPOR-SOLID REPLACEMENT AND PROPERTIES OF HETERO-ATOM ALUMINO-PHOSPHATE MOLECULAR SIEVES |
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| Zuo Lihu,Pang Wengqin,Qiu Shilun,Men Xianping and Chen Kezeng.STUDY ON VAPOR-SOLID REPLACEMENT AND PROPERTIES OF HETERO-ATOM ALUMINO-PHOSPHATE MOLECULAR SIEVES[J].Chinese Journal of Inorganic Chemistry,1988,4(2):74-81. |
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| Authors: | Zuo Lihu Pang Wengqin Qiu Shilun Men Xianping and Chen Kezeng |
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| Institution: | Institute of Synthetic and Catalytic Chemistry of Jilin University, Changchun,Institute of Synthetic and Catalytic Chemistry of Jilin University, Changchun,Institute of Synthetic and Catalytic Chemistry of Jilin University, Changchun and Institute of Synthetic and Catalytic Chemistry of Jilin University, Changchun |
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| Abstract: | In this paper, Sapo-5, Tapo-5,Bapo-5 hetero-atom aluminophosphate molecular sieves were synthesized by Vapor-Solid phase replacement. The crystal morphology, ability of adsorption, thermal stability of them were studied. The structure of aluminophosphate hetero-atom molecular sieves has been also researched with ESR, XPS, XEP, IR, MAS. NMR and XRD. The results show that titanium, silicon, boron were introduced to the framework of molecular sieves. |
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| Keywords: | vapor-solid phase replacement hetero-atom alumino-phosphate molecular sieve |
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