| 新颖的镧-2-氟苯甲酸及2，2′-联吡啶配合物的合成与晶体结构 |
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| 引用本文： | 李夏. 新颖的镧-2-氟苯甲酸及2，2′-联吡啶配合物的合成与晶体结构[J]. 无机化学学报, 2007, 23(3): 489-493 |
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| 作者姓名： | 李夏 |
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| 作者单位： | 首都师范大学化学系,北京100037 |
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| 基金项目： | 北京市教委中青年骨干教师培养计划人选者经费资助项目 |
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| 摘 要： | 2-fluorobenzoic acid (2-HFBA) and 2,2′-bipyridine (2,2′-bpy) was used as ligands to react with lanthanum to obtain a complex, [La(2-FBA)3·(2,2′-bpy)]2. The structure of the complex contains three independent molecules. In two of them, the two central metal ions are connected together through four 2-FBA groups by bidentate bridging and chelating-bridging two modes. In another, the two central metal ions are connected together through four bidentate bridging 2-FBA groups. CCDC: 237658.
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| 关 键 词： | 镧配合物； 2-氟苯甲酸； 2，2′-联吡啶； 晶体结构 |
| 文章编号： | 1001-4861(2007)03-0489-05 |
| 修稿时间： | 2006-07-18 |
Synthesis,Crystal Structure and Properties of a Novel Lanthanum 2-fluorobenzoate Complex Containing 2,2''''-bipyridine |
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| LI Xia. Synthesis,Crystal Structure and Properties of a Novel Lanthanum 2-fluorobenzoate Complex Containing 2,2''''-bipyridine[J]. Chinese Journal of Inorganic Chemistry, 2007, 23(3): 489-493 |
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| Authors: | LI Xia |
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| Affiliation: | Department of Chemistry, Capital Normal University, Beijing 100037 |
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| Abstract: | 2-fluorobenzoic acid(2-HFBA)and 2,2'-bipyridine(2,2'-bpy)was used as ligands to react with molecules.In two of them,the two central metal ions are connected together through four 2-FBA groups by bidentate bridging and chelating-bridging two modes.In another,the two central metal ions are connected together through four bidentate bridging 2-FBA groups. |
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| Keywords: | lanthanum complex 2-fluorobenzoate 2,2'-bipyridine crystal structure |
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