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Synthesis and size differentiation of Ge nanocrystals in amorphous SiO2
Authors:S. Ağan  A. Çelik-Aktaş  J.M. Zuo  A. Dana  A. Aydınlı
Affiliation:(1) Department of Materials Science and Engineering, University of Illinois, 1304 West Green Street, Urbana, IL 61801, USA;(2) Department of Nuclear, Plasma and Radiological Engineering, University of Illinois, 103 South Goodwin, Urbana, IL 61801, USA;(3) Physics Department, Bilkent University, 06800 Ankara, Turkey;(4) Physics Department, Kırıkale University, 71451 Kırıkale, Turkey
Abstract:Germanosilicate layers were grown on Si substrates by plasma enhanced chemical vapor deposition (PECVD) and annealed at different temperatures ranging from 700–1010 °C for durations of 5 to 60 min. Transmission electron microscopy (TEM) was used to investigate Ge nanocrystal formation in SiO2:Ge films. High-resolution cross section TEM images, electron energy-loss spectroscopy and energy dispersive X-ray analysis (EDX) data indicate that Ge nanocrystals are present in the amorphous silicon dioxide films. These nanocrystals are formed in two spatially separated layers with average sizes of 15 and 50 nm, respectively. EDX analysis indicates that Ge also diffuses into the Si substrate. PACS 68.73.Lp; 61.46.Hk; 61.46.-w; 68.65.Hb; 61.82.Rx
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