| 铜催化芳基(或烷基)卤化物选择性烯丙基化反应研究 |
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| 引用本文： | 韩博士,时郑,何慧红,张兴华. 铜催化芳基(或烷基)卤化物选择性烯丙基化反应研究[J]. 有机化学, 2021, 0(2): 695-701 |
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| 作者姓名： | 韩博士 时郑 何慧红 张兴华 |
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| 作者单位： | 上海应用技术大学化学与环境工程学院;宁波大学新药技术研究院 |
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| 基金项目： | 国家自然科学基金(No.21871182)资助项目。 |
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| 摘 要： | 以溴代芳烃和烯丙基乙酸酯为反应原料,发展了一种铜催化高效构建碳碳键的交叉偶联方法.该方法通过“一锅法”策略,有效避免了预制金属有机试剂的使用,在较温和条件下即可实现烯丙基类化合物的高区域选择性制备.
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| 关 键 词： | 铜催化 烯丙基化 区域选择性 |
Study on the Copper-Catalyzed Selective Allylation of Aryl(or Alkyl)Halides |
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| Han Boshi,Shi Zheng,He Huihong,Zhang Xinghua. Study on the Copper-Catalyzed Selective Allylation of Aryl(or Alkyl)Halides[J]. Chinese Journal of Organic Chemistry, 2021, 0(2): 695-701 |
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| Authors: | Han Boshi Shi Zheng He Huihong Zhang Xinghua |
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| Affiliation: | (School of Chemical and Environmental EngineeringShanghai Institute of Technology,Shanghai 201418;Institute of Drug Discovery Technology Ningbo Universiy,Ningbo,Zhejiang 315211) |
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| Abstract: | A practical method for the Cu-catalyzed coupling of aryl(or alkyl) halides with allylic acetates was described. This procedure effectively avoids the use of preformed Grignard reagent and affords allyl products with high to excellent regioselectivity under relatively mild condition. |
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| Keywords: | copper-catalyzed allylation regioselectivity |
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