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Bis(oxalato)chromium(III) complexes: Versatile tectons in designing heterometallic coordination compounds |
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| Authors: | Gabriela Marinescu Marius Andruh Francesc Lloret Miguel Julve |
| Institution: | 1. Institute of Physical Chemistry of the Romanian Academy, Coordination Chemistry Laboratory, Spl. Independentei nr. 202, 060021 Bucharest, Romania;2. Inorganic Chemistry Laboratory, Faculty of Chemistry, University of Bucharest, Str. Dumbrava Rosie nr. 23, 020464 Bucharest, Romania;3. Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), C/Catedrático José Beltrán no. 2, 46980 Paterna (Valencia), Spain |
| Abstract: | The mononuclear oxalato-containing chromium(III) complexes of general formula Cr(AA)(C2O4)2]? (AA = α-diimine type ligand) are able to produce a large variety of heterometallic complexes by acting as ligands towards either fully solvated metal ions or preformed cationic complexes with available coordination sites. This review focuses on the structural diversity of the polynuclear complexes (oligonuclear and coordination polymers) which are generated by the bis(oxalato)chromate(III) species, with a special emphasis to their magnetic properties. |
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