Polymerization catalysis with transition metal amidinate and related complexes |
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| Authors: | Scott Collins |
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| Institution: | 1. Department of Polymer Science, The University of Akron, Akron, OH 44325-3909, United States;2. Department of Chemistry, University of Waterloo, Waterloo, ON, Canada N2L 3G1 |
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| Abstract: | Applications of transition metal amidinate RC(NR′)2], guanidinate and amidopyridine complexes to olefin coordination polymerization are reviewed. In addition, the use of complexes, featuring closely related ligands, such as phosphonamide or iminophosphonamide R2P(NR′)2], in olefin polymerization is highlighted. Some of these complexes have also been investigated in the stereoregular polymerization of styrene and conjugated dienes, whereas more recent work has focused on controlled ring-opening polymerization of lactones and lactides. |
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