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Palladium-catalyzed asymmetric allylic substitutions in the presence of chiral phosphine-imine type ligands |
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| Authors: | Yin-Wei Sun Jia-Jun Jiang Mei-Xin Zhao Fei-Jun Wang Min Shi |
| Affiliation: | 1. Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Mei Long Lu, Shanghai 200237, China;2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China |
| Abstract: | Chiral bidentate phosphine-imine type ligand L9 is fairly effective in the asymmetric allylic substitution of 1,3-diphenylpropenyl acetate with dimethyl malonate to give the corresponding adduct in moderate yield and good ee. |
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