Thermal conductivity of glassy primary mono-hydroxylalcohols |
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Authors: | AI Krivchikov OA Korolyuk IV Sharapova ОО Romantsova FJ Bermejo C Cabrillo R Fernandez-Perea I Bustinduy |
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Institution: | 1. B. Verkin Institute for Low Temperature Physics and Engineering of NAS Ukraine, 47 Lenin Ave., Kharkov 61103, Ukraine;2. Instituto de Estructura de la Materia, CSIC, and Departamento Electricidad y Electrónica-Unidad Asociada CSIC, Facultad de Ciencia y Tecnología, Universidad del País Vasco/EHU, P.O. Box 644, E-48080 Bilbao, Spain |
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Abstract: | Thermal conductivity κ(T) data for homologous series of primary mono-hydric alcohols – methanol, ethanol, 1-propanol, 1-butanol – within their molecular glass states are analyzed within the temperature region stretching from 2 K up to the glass transition Tg. Below 7 K κ(T) increases with the number of carbon atoms in the molecule. Furthermore, its temperature dependence exhibits a behavior akin to that predicted by the phenomenological model of soft potentials (SPM). The data are then rationalized in terms of the SPM parameters such as characteristic energy W and the parameter ¯С which measures the strength of the coupling of acoustic modes with two-level systems. The dependence of such parameters upon the molecular mass of the alcohol seems to agree with the SPM predictions. The parameters ¯С and W were used to calculate the boson peak energies. The values obtained agree well with literature data. |
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