Spacer directed metallo-supramolecular assemblies of pyridine carboxylates |
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| Authors: | Peili Teo T.S. Andy Hor |
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| Affiliation: | 1. California Institute of Technology, Division of Chemistry and Chemical Engineering, 1200 E. California Blvd., MC 164-30, Pasadena, CA 91125, USA;2. Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore;3. Institute of Materials Research and Engineering, Agency for Science, Technology and Research, 3 Research Link, Singapore 117602, Singapore |
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| Abstract: | N,O-donating spacers are members of a class of ambidentate donors used in supramolecular self-assemblies. The skeletal adaptability and coordination flexibility of these ligands enable them to support a myriad of discrete molecular systems and extended network materials. This review focuses on pyridinecarboxylates as a representative of N,O-hetero-donating spacers and describes their recent developments in the coordination assemblies and highlights their functions and potential applications. |
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