| Stannous-acetylacetonate： A new catalyst for poly（trimethylene terephthalate） synthesis |
| |
| 引用本文： | Shu Yong Jia Yu Rong Ren Liang Ming Liu Dan Zhang Yi Zeng Gong Ying Wang. Stannous-acetylacetonate： A new catalyst for poly（trimethylene terephthalate） synthesis[J]. 中国化学快报, 2007, 18(7): 827-830. DOI: 10.1016/j.cclet.2007.05.019 |
| |
| 作者姓名： | Shu Yong Jia Yu Rong Ren Liang Ming Liu Dan Zhang Yi Zeng Gong Ying Wang |
| |
| 作者单位： | Shu Yong Jia a，c，Yu Rong Ren b，Liang Ming Liu a，Dan Zhang a，c，Yi Zeng a，Gong Ying Wang a，* a Chengdu Institute of Organic Chemistry，Chinese Academy of Sciences，Chengdu 610041，China b College of Chemistry，Jilin Normal University，Siping 136000，China c Graduate University of Chinese Academy of Sciences，Beijing 100039，China |
| |
| 基金项目： | 中国科学院研究生院创新研究基金 |
| |
| 摘 要： | Stannous-acetylacetonate was prepared efficiently and characterized by 1H NMR and FT-IR. Its catalytic activity for poly(trimethylene terephthalate) (PTT) synthesis was investigated. By this catalyst, the degree of esterification of pure terephthalic acid was up to 91.7% after reaction at 260°C for 2 h, while the intrinsic viscosity and content of ter- minal carboxyl groups of the corresponding PTT polymerized at 260°C, 60 Pa for 2 h was 0.8816 dL/g and 17 mol/t, respectively. Stannous-acetylacetonate was more active and promising than tetrabutyl titanate and stannous octoate for PTT synthesis.
|
| 关 键 词： | 聚（三甲烯对苯二酸盐酯） 锡-乙酰丙酮化物 1 3-丙二醇 聚合反应 |
| 收稿时间： | 2007-02-27 |
| 修稿时间： | 2007-02-27 |
Stannous-acetylacetonate: A new catalyst for poly(trimethylene terephthalate) synthesis |
| |
| Shu Yong Jia,Yu Rong Ren,Liang Ming Liu,Dan Zhang,Yi Zeng,Gong Ying Wang. Stannous-acetylacetonate: A new catalyst for poly(trimethylene terephthalate) synthesis[J]. Chinese Chemical Letters, 2007, 18(7): 827-830. DOI: 10.1016/j.cclet.2007.05.019 |
| |
| Authors: | Shu Yong Jia Yu Rong Ren Liang Ming Liu Dan Zhang Yi Zeng Gong Ying Wang |
| |
| Affiliation: | 1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China;2. College of Chemistry, Jilin Normal University, Siping 136000, China;3. Graduate University of Chinese Academy of Sciences, Beijing 100039, China |
| |
| Abstract: | Stannous-acetylacetonate was prepared efficiently and characterized by 1H NMR and FT-IR. Its catalytic activity for poly(trimethylene terephthalate) (PTT) synthesis was investigated. By this catalyst, the degree of esterification of pure terephthalic acid was up to 91.7% after reaction at 260 °C for 2 h, while the intrinsic viscosity and content of terminal carboxyl groups of the corresponding PTT polymerized at 260 °C, 60 Pa for 2 h was 0.8816 dL/g and 17 mol/t, respectively. Stannous-acetylacetonate was more active and promising than tetrabutyl titanate and stannous octoate for PTT synthesis. |
| |
| Keywords: | Poly(trimethylene terephthalate) Stannous-acetylacetonate 1,3-Propanediol |
| 本文献已被 CNKI 维普 万方数据 ScienceDirect 等数据库收录！ |
