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Proton conduction in materials comprising conducting domains with widths less than 6 nm
Authors:Nitash P. Balsara  Keith M. Beers[Author vitae]
Affiliation:aDepartment of Chemical Engineering, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720, USA;bMaterials Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720, USA;cEnvironmental Energy Technologies Division, Lawrence Berkeley National Laboratory, University of California, 201C Gilman Hall, Berkeley, CA 94720, USA
Abstract:We review the literature on proton conductivity and water uptake of composite polymer electrolyte membranes comprising bicontinuous hydrophilic and hydrophobic domains with well-controlled geometries. Both quantities appear to be enhanced when the width of the hydrophilic channels is smaller than 6 nm.
Keywords:Polymer   Electrolyte   Membranes   Water retention   Proton conductivity   Microphases
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