Phase-transfer catalysis in reactions with the participation of polyvinyl chloride |
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Authors: | G. V. Leplyanin V. N. Salimgareeva |
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Affiliation: | (1) Institute of Organic Chemistry, Ufa Scientific Center of Ural Branch of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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Abstract: | When polyvinyl chloride is dehydrochlorinated under conditions of phase transfer catalysis, the nature of the interface determines the supramolecular structure of the synthesized polyacetylene, the packing density of crystalline regions in the polyacetylene, and the chemical properties of the polymer. The ionic mechanism of catalysis of these reactions has been established.This review is based on materials reported at the Conference Phase-Transfer Catalysis: New Ideas and Methods(March, 1994).Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1886–1894, October, 1995. |
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Keywords: | phase-transfer catalysis polyvinyl chloride polyacetylene interface suprmolecular structure dehydrochlorination |
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