|
|||||
|
|
Intramolecular cyclisation of isosorbide by dimethylcarbonate chemistry |
|
| Authors: | Pietro Tundo Fabio Aricò Guillaume Gauthier Agostino Baldacci |
| Affiliation: | 1. Interuniversity Consortium “Chemistry for the Environment”, Via delle Industrie, 21/8 30175 Marghera, Venice, Italy;2. Ca’ Foscari Università di Venezia, Dipartimento Scienze Ambientali, Dorsoduro 2137, 30123 Venice, Italy;3. École nationale supérieure de chimie de Paris (ENSCP – Chimie ParisTech), 11, rue Pierre-et-Marie-Curie, 75005 Paris, France;4. Ca’ Foscari Università di Venezia, Dipartimento di Chimica Fisica, Dorsoduro 2137, 30123 Venice, Italy |
| Abstract: | In this work the synthesis of a tricyclic isosorbide derivative in moderate yield directly from the dicarboxymethyl isosorbide in a continuous-flow apparatus is reported. The tricyclic structure has been isolated as pure and fully characterized. This product confirms the potentiality of dimethylcarbonate (DMC) as dehydrating agent also for complicated structure and opens up further investigation and application of DMC chemistry on renewable starting materials. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |