Energy partitioning and reaction dynamics in the chemiluminescent channel of the reaction: HS + O3 → HSO* + O2 |
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| Authors: | D.J.W. Kendall,J.J.A. O&#x Brien,J.J. Sloan,R.Glen Macdonald |
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| Affiliation: | National Research Council Canada, 100 Sussex Drive, Ottawa, Ontario, Canada K1A 0R6;Atomic Energy of Canada Ltd., Chalk River Nuclear Laboratories, Chalk River, Canada K0J 1J0 |
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| Abstract: | The title reaction forms electronically excited HSO(Ã2A′) directly, with considerable vibrational and rotational excitation as well. The internal excitation of the HSO fragment is the maximum possible consistent with the concurrent formation of an O2(1Δg) molecule as the other reaction product. The observed vibrational excitation peaks in the υ′= 2 level of the υ3 mode. No evidence about possible excitation of the other vibrational modes of HSO could be obtained. |
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