Theory of activated rate processes: Coupled modes |
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Authors: | Benny Carmeli Abraham Nitzan |
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Affiliation: | Department of Chemistry, Tel-Aviv, University, Tel Aviv, 69978, Israel |
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Abstract: | The thermally activated escape rate of a classical particle out of a potential well is studied in a simple model which includes coupling between the escape (reactive) coordinate and another coordinate. The main effect of the non-reactive coordinate is to open a new (non-markovian) channel between the reactive coordinate and the thermal bath. |
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