A flowing afterglow study of uranium tetraborohydride |
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| Authors: | Lucia M Babcock Charles R Herd Gerald E Streit |
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| Institution: | Department of Chemistry. Louisiana State University, Baton Rouge, Louisiana 70803, USA;CHM-2 Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA |
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| Abstract: | Ionization-fragmentation of uranium(IV) tetraborohydride, U(BH4)4, by He+ and by N+/N2+ yields, predominantly, U(BH5)+ and U(B2H8)+, respectively. Attachment of thermal electrons yields U(BH4)4? and ions of 1, 2, and 3 mass units less. Fluoride transfer with SF6?, BF4?, and UFn? (n = 5–7) and reactions with other small ions (O?, O2?, NO2?, F?, Cl?, O2+) are described. |
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