Time-resolved resonance raman spectra and decay kinetics of triplet anthracene in fluid media |
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Authors: | GNR Tripathi MR Fisher |
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Institution: | Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556, USA |
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Abstract: | Reported here are the time-resolved resonance Raman spectra and decay kinetics of the lowest triplet state (3B2u+) of anthracene-h10 and anthracene-d10 molecules in fluid media at room temperature. The triplet population (≈3 × 10?5 M) is observed to decay at microsecond times by triplet—triplet annihilation. Vibrational assignments for the observed Raman bands are proposed. |
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