Rhenocene: Magnetic circular dichroism and laser-induced fluorescence in nitrogen matrices |
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| Authors: | PAnthony Cox Peter Grebenik Robin N Perutz Robin G Graham Roger Grinter |
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| Institution: | Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR, UK;School of Chemical Sciences, University of East Anglia, Norwich NR4 7TJ, UK |
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| Abstract: | Rhenocene generated in nitrogen matrices by photolysis of Re(η-C5H5)2H, shows an intense, structured progression in magnetic circular dichroism. The non-linear magnetic field and temperature dependence of the dichroism indicate a 2E2g(= 5/2) ground state. Lazer-induced fluorescence is used to establish the (0.0) component of the absorption band and to derive the energies of three totally symmetric vibrational fundamentals. |
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| Keywords: | Address correspondence to RNP at Department of Chemistry University of York Heslington York YOI 5DD UK |
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