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| Synthesis and Structure of a Cp^＊Ir Half-sandwich Complex Containing Azido and Bis（diphenylthiophosphoryl）amide Ligands | |
| 引用本文： | 吴芳辉,段泰轲,陆路德,张千峰.Synthesis and Structure of a Cp^＊Ir Half-sandwich Complex Containing Azido and Bis（diphenylthiophosphoryl）amide Ligands[J].结构化学,2010,29(1):39-42. |
| 作者姓名： | 吴芳辉 段泰轲 陆路德 张千峰 |
| 作者单位： | Material;Chemistry;Laboratory;Nanjing;University;Science;Technology;Institute;Molecular;Engineering;Applied;Anhui; |
| 基金项目： | supported by the National Natural Science Foundation of China;;the Program for New Century Excellent Talents in University (20771003 and NCET-06-0556) |
| 摘 要： | The title complex CpIr{N(Ph2PS)2}(N3)](N(Ph2PS)2=bis(diphenylthiophosphoryl)amide,Cp=pentamethylcyclopentadienyl) has been prepared and characterized by X-ray diffraction analysis.It crystallizes in monoclinic,space group P21/n with a=11.6946(1),b=18.9273(2),c=15.7859(1),β=105.731(1)°,V=3363.29(5)3,Z=4,Mr=817.92,Dc=1.615g/cm3,μ(MoKα)=4.219 mm-1,F(000)=1624,S=1.028,the final R=0.0355 and wR=0.0848 for 5987 observed reflections with Ⅰ 2σ(Ⅰ) and 363 variables.The molecular structure of 1 consists of discrete monomeric molecule with a distorted octahedral configuration around the iridium atom,having a Cp ring at one face and bonded with a chelating bis(diphenylthiophosphoryl)amide group as well as a terminal azido ligand.The average Ir-S and Ir-N bond lengths are 2.416(1) and 2.121(5),respectively. |
| 关 键 词： | 酰胺基 体结构 配体 叠氮 铱 合成 复合 夹心 |
Synthesis and Structure of a Cp~* Ir Half-sandwich Complex Containing Azido and Bis(diphenylthiophosphoryl)amide Ligands |
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| WU Fang-Hui,DUAN Tai-Ke,LU Lu-De,ZHANG Qian-Feng.Synthesis and Structure of a Cp~* Ir Half-sandwich Complex Containing Azido and Bis(diphenylthiophosphoryl)amide Ligands[J].Chinese Journal of Structural Chemistry,2010,29(1):39-42. | |
| Authors: | WU Fang-Hui DUAN Tai-Ke LU Lu-De ZHANG Qian-Feng |
| Institution: | 1. Material Chemistry Laboratory,Nanjing University of Science and Technology,Nanfing 210094,China;Institute of Molecular Engineering and Applied Chemistry,Anhui University of Technology,Ma'anshan,Anhui 2. Institute of Molecular Engineering and Applied Chemistry,Anhui University of Technology,Ma'anshan,Anhui 243002,China 3. Material Chemistry Laboratory,Nanjing University of Science and Technology,Nanfing 210094,China |
| Abstract: | The title complexCp~*Ir{N(Ph_2PS)_2}(N_3)](N(Ph_2PS)_2=bis(diphenylthiophosphoryl)amide,Cp~*=pentamethylcyclopentadienyl)has been prepared and characterized by X-ray diffraction analysis.It crystallizes in monoclinic,space group P2_1/n with a=11.6946(1),b=18.9273(2),c=15.7859(1)(A),β=105.731(1)°,ν=3363.29(5)(A)~3,Z=4,M_r=817.92,D_c=1.615g/cm~3,μ(MoKα)=4.219 mm~(-1),F(000)=1624,S=1.028,the final R=0.0355 and wR=0.0848 for 5987 observed reflections with,I＞2 σ(I) and 363 variables.The molecular structure of 1 consists of discrete monomerie molecule with a distorted octahedral configuration around the iridium atom,having a Cp~* ring at one face and bonded with a chelating bis(diphenylthiophosphoryl)amide group as well as a terminal azido ligand.The average Ir-S and Ir-N bond lengths are 2.416(1)and 2.121(5)(A),respectively. |
| Keywords: | iridium pentamethylcyclopentadienyl azide synthesis crystal structure bis(diphenylthiophosphoryl)amide ligand |
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