Synthesis of the C(1)-C(25) fragment of amphidinol 3: application of the double-allylboration reaction for synthesis of 1,5-diols |
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| Authors: | Flamme Eric M Roush William R |
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| Affiliation: | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055, USA. |
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| Abstract: | [structure: see text] A synthesis of the C(1)-C(25) fragment of amphidinol 3 is described. The synthesis features two applications of double allylboration reaction methodology for the highly stereoselective synthesis of 1,5-diol units in the C(1)-C(15) segment. |
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