| 喹啉类离子化合物的合成及其室温促进下Knoevenagel反应的研究 |
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| 引用本文： | 吴坤,李存雄. 喹啉类离子化合物的合成及其室温促进下Knoevenagel反应的研究[J]. 有机化学, 2011, 31(1): 119-122 |
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| 作者姓名： | 吴坤 李存雄 |
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| 作者单位： | 贵州省山地环境信息系统与生态环境保护重点实验室,贵阳,550001 |
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| 基金项目： | 贵州省优秀科技教育人才省长专项基金项目 |
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| 摘 要： | 以喹啉为原料, 在温和条件下制得喹啉类离子化合物1～9, 并在室温下将其用于Knoevenagel缩合反应, 以80%～95%的收率高效生成相应的烯腈a～f, 离子化合物经过简单处理即可重复使用.
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| 关 键 词： | 喹啉 离子化合物 室温 Knoevenagel |
| 收稿时间： | 2010-04-16 |
| 修稿时间： | 2010-08-07 |
Synthesis of Quinolinium lonic Compounds and Their Promotion in Knoevenagel Reaction at Room Temperature |
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| Wu Kun,Li Cunxiong. Synthesis of Quinolinium lonic Compounds and Their Promotion in Knoevenagel Reaction at Room Temperature[J]. Chinese Journal of Organic Chemistry, 2011, 31(1): 119-122 |
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| Authors: | Wu Kun Li Cunxiong |
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| Affiliation: | (Key Laboratory for Information System of Mountainous Area and Protection of Ecological Environment of Guizhou Prov-ince, Guiyang 550001) |
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| Abstract: | Nine kinds of quinolinium ionic compounds were synthesized using quinolin as starting material. Their promotions in Knoevenagel condensation reaction of aromatic aldehydes and malononitrile were also discussed. The yields were between 80%～95%, and the ionic compounds can be used repeatedly. |
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| Keywords: | quinolinium ionic compound room temperature Knoevenagel |
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