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| 二芳基汞的合成 | |
| 引用本文： | 王千杰,胡宏纹. 二芳基汞的合成[J]. 无机化学学报, 1987, 3(3): 78-81 |
| 作者姓名： | 王千杰 胡宏纹 |
| 作者单位： | 宁夏大学化学系(王千杰)，南京大学化学系(胡宏纹) |
| 摘 要： | 将氯化重氮苯的溶液加入氯化汞、维生素C、丙酮和少量氯化铜的混合物中,得到80％的氯化苯汞;如在反应混合物中补加维生素C、氯化铜和浓氨水,则得到二苯汞。用同样的方法制备了其他的二芳基汞,并讨论了反应可能的机理。 |
| 关 键 词： | 二芳基汞 维生素C 氯化亚汞 重氮盐 |
| 收稿时间： | 1986-08-29 |
PREPARATION OF DIARYLMERCURY |
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| Wang Qianjie and Hu Hongweng. PREPARATION OF DIARYLMERCURY[J]. Chinese Journal of Inorganic Chemistry, 1987, 3(3): 78-81 | |
| Authors: | Wang Qianjie and Hu Hongweng |
| Affiliation: | Department of Chemistry, Ningxia University and Department of Chemistry, Nanjing University |
| Abstract: | Phenylmercuric chloride was obtained in 80% yield by adding ben-zeaediazonium chloride solution to a mixture of mercuric chloride, ascorbic acid, acetone and a small amount of cupric chloride. When the reaction mixture was treated with ascorbic acid, cupric chloride and ammonia diphenylmercury was formed. The same method was used for the preparation of other diarylmercury. The possible mechanism of this reaction was also discussed. |
| Keywords: | diarylmercury ascorbic acid mercurous chloride diazonium salt |
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