| 直链淀粉-三(3,5-二甲基苯基氨基甲酸酯)手性固定相分离硒代甘油醚对映体 |
| |
| 引用本文： | 于兆文,刘月启,刘快之,蒋生祥,陈立仁. 直链淀粉-三(3,5-二甲基苯基氨基甲酸酯)手性固定相分离硒代甘油醚对映体[J]. 分析化学, 1999, 27(10): 1164-1167 |
| |
| 作者姓名： | 于兆文 刘月启 刘快之 蒋生祥 陈立仁 |
| |
| 作者单位： | 1. 河南大学化学化工学院,开封,475001
2. 中国科学院兰州化学物理研究所,兰州,730000 |
| |
| 基金项目： | 中国科学院重点基金资助课题 |
| |
| 摘 要： | 合成出了直链淀粉-三(3,5-二甲基苯基氨基甲酸酯)手性固定相.用该固定相首次拆分了一系列硒代甘油醚对映异构体.讨论了流动相组成和样品结构对保留和拆分的影响.
|
| 关 键 词： | 手性固定相 对映体分离 高效液相色谱 |
| 修稿时间： | 1998-11-16 |
Optical Resolution of Glycerin Selenides with Amylose-tris- (3,5-dimethylphenylcarbamate) Chiral Stationary Phase |
| |
| Yu Zhaowen,Liu Yueqi,Liu Kuaizhi,Jiang Shengxiang,Chen Liren. Optical Resolution of Glycerin Selenides with Amylose-tris- (3,5-dimethylphenylcarbamate) Chiral Stationary Phase[J]. Chinese Journal of Analytical Chemistry, 1999, 27(10): 1164-1167 |
| |
| Authors: | Yu Zhaowen Liu Yueqi Liu Kuaizhi Jiang Shengxiang Chen Liren |
| |
| Abstract: | A chiral stationary phase was prepared by coating amylose-tas(3,5-dimethylphenylcarbamate) onto aminopropylated silica gel. It was used for the optical resolution of a series of glycerin monoselenides and glycerin bisulfide. All the enantiomers of the monoselenides examined could be resolved but that of the bisulfides couldn' t. The structural character of the samples dial influence chiral resolution as discussed. An interaction model between the stationary phase and the samples was presented. |
| |
| Keywords: | Chiral stadonarty phase high-performance liquid chromatography enantioseparation |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
