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六氢吡啶团簇的研究
引用本文:陈文武,高毅勤,吴国胜,杨达林,盛六四,武国华,叶为全,张允武. 六氢吡啶团簇的研究[J]. 物理化学学报, 1996, 12(12): 1067-1070. DOI: 10.3866/PKU.WHXB19961203
作者姓名:陈文武  高毅勤  吴国胜  杨达林  盛六四  武国华  叶为全  张允武
作者单位:The State Key Laboratory of Molecular Reaction Dynamics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,National Laboratory of Synchrotron Radiation,University of Science and Technology of China,Hefei 230027
基金项目:国家自然科学基金,国家同步辐射实验室开放基金
摘    要:

关 键 词:六氢吡啶  分子团簇  氢键  环状和链状结构  
收稿时间:1996-09-14
修稿时间:1996-10-09

The Study of the 6-H Pyridine Clusters
Chen Wen-Wu,Gao Yi-Qin,Wu Guo-Sheng,Yang Da-Lin,Sheng Liu-Si,Wu Guo-Hua,Ye Wei-Quan,Zhang Yun-Wu. The Study of the 6-H Pyridine Clusters[J]. Acta Physico-Chimica Sinica, 1996, 12(12): 1067-1070. DOI: 10.3866/PKU.WHXB19961203
Authors:Chen Wen-Wu  Gao Yi-Qin  Wu Guo-Sheng  Yang Da-Lin  Sheng Liu-Si  Wu Guo-Hua  Ye Wei-Quan  Zhang Yun-Wu
Affiliation:The State Key Laboratory of Molecular Reaction Dynamics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080|National Laboratory of Synchrotron Radiation,University of Science and Technology of China,Hefei 230027
Abstract:The 6H-pyridine clusters have been studied by the TOF mass spectrometry, the VUV from synchrotron radiation and the molecular beam technique. Three-type clusters are observed in the VUV photoionization mass spectroscopy: Pn+(n=2-5,P stands for 6H-pyridine molecule), PnH+ (n=2-4) and Pn (H2O)m+(n=4,5, m=1;n=6, m=1,2). The PnH+ clusters may have the chain structures, the Pn+ and Pn(H2O)m+ clusters may have the cyclic structures, all of these are formed by the hydrogen-bond.
Keywords:6H-pyridine   Molecular cluster   Hydrogen bond   Cycle and chain structure  
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