| 阳极氧化水解法制备TiO2纳米膜 |
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| 引用本文： | 戴松元,王瑜,邬钦崇,王孔嘉,霍裕平.阳极氧化水解法制备TiO2纳米膜[J].物理化学学报,1996,12(8):758-760. |
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| 作者姓名： | 戴松元 王瑜 邬钦崇 王孔嘉 霍裕平 |
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| 作者单位： | Institute of Plasma Physics,Academia,Sinica,Hefei 230031 |
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| 基金项目： | 中国科学院院长重点基金，“化学太阳能光电池”资助 |
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| 摘 要： | TiO2在光电化学电池领域已成为比较重要的半导体材料，自从1972年，Fuishima和Honda首次把TiO2电极用于光电解水以来，人们已经使用多种方法，如化学气相沉积、TiO2粉的烧结、RF射频溅射、等离子体喷涂或用胶体TiO2涂膜等各种方法，来制备单晶（金红石），多晶（金红石、锐钛矿
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| 关 键 词： | 阳极氧化 水解 纳米晶体 太阳能电池 |
| 收稿时间： | 1995-12-06 |
| 修稿时间： | 1996-03-22 |
Preparation of Nanometer TiO_2 Films by Anodic Oxidative Hydrolysis |
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| Dai Songyuan, Wang Yu, Wu Qinchong, Wang Konajia, Huo Yuping.Preparation of Nanometer TiO_2 Films by Anodic Oxidative Hydrolysis[J].Acta Physico-Chimica Sinica,1996,12(8):758-760. |
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| Authors: | Dai Songyuan Wang Yu Wu Qinchong Wang Konajia Huo Yuping |
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| Institution: | Institute of Plasma Physics,Academia,Sinica,Hefei 230031 |
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| Abstract: | Ti(IV) oxide has been an important semi-conductor material in photoelectrochemical cell, especially in the area of developing photochemical nanocrystalline solar cell. The TiO2 films were deposited on SnO2 (F-doped) glass electrodes by anodic oxidative hydrolysis of acidic aqueous TiCl3 solutions. The films are uniform in thickness, have an average size of approximately 20nm, and have the anatase structure after annealing at 450℃. The method of anodic oxidative hydrolysis, the method of electrodepositing high pure TiO2 (anatase) on transparent conducting oxide (TCO) glass, condition of producing TiO2 film, and some character of the film have also been investigated. |
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| Keywords: | Anodic oxidative Hydrolysis Nanocrystalline Solar cell |
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