| 微波合成均分散胶体高分子微球 |
| |
| 引用本文： | 张文敏,唐业仓,张洪涛,高均,吴奇.微波合成均分散胶体高分子微球[J].物理化学学报,1996,12(10):943-945. |
| |
| 作者姓名： | 张文敏 唐业仓 张洪涛 高均 吴奇 |
| |
| 作者单位： | Department of Chemistry,The Anhui Normal University,Wuhu 241000,Department of Chemistry,The Chinese University of Hong Kong |
| |
| 摘 要： | 1947年美国密西很大学的研究人员在电子显微镜下首次发现，聚苯乙烯胶乳粒子是理想的均分散微球．很快地，这些颗粒成为大家公认的电子显微镜内标物，并开发出许多其它用途，如标定仪器、测定膜厚、孔隙、血管管径、填充色谱柱、检验电泳方法，以及用于蛋白质分离、检测脑膜炎、妊娠等．微波辐照对于许多有机化学反应有着明显的加速作用．与传统的方法相比，具有高效、节能、无环境污染等优点问．Murr阿等人同首次报导了用微波辐照的方法制备均分散胶体高分子微球．合成反应的时间由传统方法的6个小时缩短到不足1小时．然而，他们在实验中…
|
| 关 键 词： | 微波反应 均分散高分子微球 聚苯乙烯 顺丁烯二酸酐 |
| 收稿时间： | 1996-03-11 |
| 修稿时间： | 1996-06-26 |
Microwave Synthesis of the Uniform Colloidal High Molecular Microballons |
| |
| Zhang Wenmin ,Tang Yecang, Zhang Hongtao.Microwave Synthesis of the Uniform Colloidal High Molecular Microballons[J].Acta Physico-Chimica Sinica,1996,12(10):943-945. |
| |
| Authors: | Zhang Wenmin Tang Yecang Zhang Hongtao |
| |
| Institution: | Department of Chemistry,The Anhui Normal University,Wuhu 241000|Department of Chemistry,The Chinese University of Hong Kong |
| |
| Abstract: | The preparation of monodisperse colloidal microlatex particles of polystyrene and poly(styrene butene diacid) by the use of microwave radiation and under normal ambient pressure is reported. There is no surfactant in the system.The total synthesis time has been reduced from more then 10h(conventional method) to less than 1 h(microwave mothod). The dynamic experimental results indicate that the reaction proecss is very sharp in comparison with conventional polymerization. No constant rate stage existed. |
| |
| Keywords: | Microwave reaction Uniform high molecular microballoons Polystyrene Anhydride of cis-butene diacid |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
| 点击此处可从《物理化学学报》下载免费的PDF全文 |
