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Ligand‐Promoted Iron(III)‐Catalyzed Hydrofluorination of Alkenes
Authors:Yongtao Xie  Peng‐Wei Sun  Yuxin Li  Siwei Wang  Mengchun Ye  Zhengming Li
Abstract:An iron‐catalyzed hydrofluorination of unactivated alkenes has been developed. The use of a multidentate ligand and the fluorination reagent N‐fluorobenzenesulfonimide (NFSI) proved to be critical for this reaction, which afforded various fluorinated compounds in up to 94 % yield.
Keywords:Alkene  Eisen  Fluor  Hydrofluorierung  Silane
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