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Total Synthesis of Actinorhodin |
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| Authors: | Mamiko Ninomiya Yoshio Ando Fumitaka Kudo Ken Ohmori Keisuke Suzuki |
| Abstract: | The enantioselective total synthesis of actinorhodin ( 1 ) is described. The synthesis features 1) dual benzyne reactions en route to the monomer, 2) the trans‐selective installation of the side chain, and 3) a regioselective oxidative dimerization. |
| Keywords: | Dimerisierung Gesamtsynthese Naturstoff Pigmente Pyranonaphthochinone |