Photochemical C−H Amination of Ethers and Geminal Difunctionalization Reactions in One Pot |
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| Authors: | Daniel Hernndez‐Guerra Anna Hlava
kov Chiranan Pramthaisong Ilaria Vespoli Radek Pohl Tom&#x; Slanina Ullrich Jahn |
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| Institution: | Daniel Hernández‐Guerra,Anna Hlavačková,Chiranan Pramthaisong,Ilaria Vespoli,Radek Pohl,Tomáš Slanina,Ullrich Jahn |
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| Abstract: | A mild, atom‐economic, and metal‐free α‐C?H amination of ethers using relatively stable nonafluorobutanesulfonyl (nonaflyl, Nf) azide as the aminating reagent to give N‐sulfonyl hemiaminals is reported. This enables unprecedented C(sp3) difunctionalization reactions, leading to diverse functionalized amino group containing compounds starting from simple ethers in one pot. |
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| Keywords: | Aminierungen C-H-Aktivierung Photoreaktionen Radikale Sulfonylazide |
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