Carbonylative C−C Bond Activation of Electron‐Poor Cyclopropanes: Rhodium‐Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides |
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| Authors: | Andrew G Dalling Takayuki Yamauchi Niall G McCreanor Lydia Cox John F Bower |
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| Abstract: | Rh‐catalyzed carbonylative C?C bond activation of cyclopropylamides generates configurationally stable rhodacyclopentanones that engage tethered alkenes in (3+1+2) cycloadditions. These studies provide the first examples of multicomponent cycloadditions that proceed through C?C bond activation of “simple” electron poor cyclopropanes. |
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| Keywords: | C-C-Aktivierung Cycloadditionen Cyclopropane Rhodium |
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