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Fe3O4@silica‐MCM‐41@DABCO: A novel magnetically reusable nanostructured catalyst for clean in situ synthesis of substituted 2‐aminodihydropyrano[3,2‐b]pyran‐3‐cyano
Authors:Khadijeh Ojaghi Aghbash  Nader Noroozi Pesyan  Hana Batmani
Abstract:DABCO (1,4‐diazabicyclo[2.2.2]octane)‐modified magnetite with silica‐MCM‐41 shell (Fe3O4@silica‐MCM‐41@DABCO) as an effective, magnetic and novel heterogeneous reusable nanocatalyst was synthesized and analysed using various techniques. Evaluation of the catalytic activity of this nanocatalyst was performed in the clean synthesis of substituted 2‐aminodihydropyrano[3,2‐b]pyran‐3‐cyano in high yields via in situ reaction of azido kojic acid, malononitrile and various aldehydes.
Keywords:2‐amino‐4,8‐dihydropyrano[3,2‐b]pyran‐3‐carbonitrile  azido kojic acid  Fe3O4@MCM‐41@DABCO  Michael addition  nanocatalyst
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