Rhodium-catalyzed 1,3-acyloxy migration and subsequent intramolecular [4+2] cycloaddition of vinylallene and unactivated alkyne |
| |
| Authors: | Huang Suyu Li Xiaoxun Lin Claire L Guzei Ilia A Tang Weiping |
| |
| Institution: | Department of Chemistry and Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, PR China. |
| |
| Abstract: | A Rh-catalyzed 1,3-acyloxy migration of propargyl ester followed by intramolecular 4+2] cycloaddition of vinylallene and unactivated alkyne was developed. This tandem reaction provides access to bicyclic compounds containing a highly functionalized isotoluene or cyclohexenone structural motif, while only aromatic compounds were observed in related transition metal-catalyzed cycloadditions. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
