Asymmetric oxidative Lewis base catalysis-unifying iminium and enamine organocatalysis with oxidations |
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| Authors: | Rueping Magnus Sundén Henrik Hubener Lukas Sugiono Erli |
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| Institution: | RWTH Aachen University, Institute of Organic Chemistry, Landoltweg 1, D-52074 Aachen, Germany. magnus.rueping@rwth-aachen.de |
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| Abstract: | Enantioselective oxidative domino reactions of allylic alcohols to functionalized aldehydes have been developed. The one pot domino oxidation-iminium activation represents a convenient strategy for the enantioselective addition of malonates to allylic alcohols and the asymmetric formation of formyl cyclopropanes. |
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