Increasing the efficiency of silicon and aluminum extraction from Volclay by a water iteration treatment for the synthesis of MCM-41 nanomaterials |
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Institution: | 1. Institute of Functional Interfaces Section, Institute of Technology Karlsruhe (KIT), 76344 Eggenstein-Leopoldshafen Karlruhe, Germany;2. Laboratoire de synthèse organique appliquée, département de chimie, faculté des sciences, université d’Oran, BP 1524, El Menaouar Oran 31000, Algeria;3. Chemistry Department, faculty of science, university of Saida, BP 138, Algeria;4. Department of Physics and CICECO, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, Portugal;5. Laboratoire “Environnement, catalyse, matériaux, environnement et chimie”, Université des sciences et de la technologie d’Oran Mohamed-Boudiaf, Oran, Algeria |
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Abstract: | This work aims to reduce the prices of a wide range of nanomaterials which are unreachable in the industry by using natural sources as silicon and aluminum precursors. In a previous work, silicon and aluminum have been extracted from Volclay after applying the alkaline fusion process at 550 °C, and a water treatment of this fused clay by adopting a weight ratio (1:4, fusion mass:H2O) to synthesize Al-MCM-41 nanomaterials. In this study, the weight ratio of fusion mass:H2O was increased to 1:8 to synthesize a highly structurally ordered MCM-41 under the same reaction conditions. The Al-MCM-41 nanomaterials are investigated by inductively coupled plasma optical emission spectrometry (ICP–OES), powder X-ray diffraction (XRD), N2 adsorption–desorption measurements and scanning electron microscopy (ESEM). As a result, the increase in the weight ratio fusion mass:H2O generates more silica and aluminum, which allows the formation of well-ordered MCM-41 nanomaterials with high pore volume (0.70 cm3/g), high surface area (1044 m2/g), and uniform mesoporous diameter (3.67 nm); as a consequence, the increase in the weight ratio fusion mass:H2O leads to an increase in the mass of Al-MCM-41 (9.3 g for 1:8 compared to 5 g for 1:4), whereas the yield of production of mesoporous materials increases to 86%. |
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Keywords: | MCM-41 Volclay Alkaline fusion Nanomaterials |
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