| 半夹心结构含1，2-二硫碳硼烷的铑配合物的合成以及结构表征 |
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| 引用本文： | 韩英锋,金国新.半夹心结构含1，2-二硫碳硼烷的铑配合物的合成以及结构表征[J].无机化学学报,2008,24(6):843-847. |
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| 作者姓名： | 韩英锋 金国新 |
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| 作者单位： | 复旦大学化学系,上海市分子催化和功能材料重点实验室,上海,200433 |
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| 摘 要： | 室温下，18-电子体系的半夹心铑配合物Cp*Rh(L)S2C2(B10H10)(L=4-ClCH2-C6H4N (2a)，4-CH3SCH2-C6H4N (2b))可以通过16-电子体系的半夹心铑配合物Cp*Rh2C2(B10H10)]与吡啶衍生物合成。化合物通过IR、1H NMR和元素分析进行了表征，并用X-射线单晶衍射测定了配合物2a和2b的单晶结构。
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| 关 键 词： | 碳硼烷 硫 半夹心铑配合物 |
| 文章编号： | 1001-4861(2008)06-0843-05 |
| 修稿时间： | 2007年10月15 |
Synthesis and Characterization of Half-sandwich Rhodium Complexes Containing 1,2-dithiolato Carborane Ligands |
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| HAN Ying-Feng and JIN Guo-Xin.Synthesis and Characterization of Half-sandwich Rhodium Complexes Containing 1,2-dithiolato Carborane Ligands[J].Chinese Journal of Inorganic Chemistry,2008,24(6):843-847. |
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| Authors: | HAN Ying-Feng and JIN Guo-Xin |
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| Institution: | Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai 200433 and Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai 200433 |
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| Abstract: | The 18-electron dithiolato carborane complexes Cp*Rh(L)2C2(B10H10) (L=4-(chloromethyl)pyridine (2a), 4-(methylthiomethyl)pyridine (2b)) were synthesized from the 16e half-sandwich rhodium complexe Cp*Rh2C2(B10H10)] and pyridine derivatives (L) at room temperature. The complexes have been fully characterized by their IR and 1H NMR spectroscopy, as well as elemental analysis. The molecular structures of 2a and 2b were established through X-ray crystal structure analysis. CCDC: 679789, 2a; 679790, 2b. |
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| Keywords: | carborane sulfur half-sandwich rhodium |
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