Advantages of digital phase-sensitive detection for upgrading an obsolete CW EPR spectrometer |
| |
Authors: | M P Tseitlin V S Iyudin O A Tseitlin |
| |
Institution: | (1) Kazan Physical-Technical Institute, Russian Academy of Sciences, Kazan, Russian Federation;(2) Kazan Physical-Technical Institute, Russian Academy of Sciences, Sibirsky trakt 10/7, 420029 Kazan, Russian Federation |
| |
Abstract: | The replacement of the commonly used analog phase-sensitive detection (PSD) by digital PSD for demodulation of electron paramagnetic
resonance (EPR) signals is suggested for upgrading of an out-of-date EPR spectrometer. Connection of the microwave bridge
output to a fast analog-digital converter (ADC) eliminates some of the spectrometer’s components: the electronics responsible
for analog PSD, ADC for sampling of demodulated signals, and a computer, as well as the usage of some of the spectrometer’s
settings. The spectrometer is reduced to a magnet, microwave bridge, and personal computer containing an ADC board. EPR signals
digitized for a set of magnetic field positions form a two-dimensional array which is stored in a personal computer. Demodulation
and filtering are done numerically to produce a conventional EPR spectrum. In comparison with analog PSD, this numerical approach
does not eliminate the out-of-phase component of the signal and the signals at the higher harmonics of the modulation frequency.
The details of modernizing the Bruker ER200E SRC EPR spectrometer are discussed to demonstrate these and other advantages
of digital demodulation. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|