Lipid spin labeling and NMR study of interaction between polyadenylic acid: polyuridilic acid duplex and egg phosphatidylcholine liposomes. Evidence for involvement of surface groups of bilayer,phosphoryl groups and metal cations |
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Authors: | R. I. Zhdanov L. A. Volkova V. V. Rodin |
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Affiliation: | 1. National Institute for Biotechnology, Nauchnyi Proezd 8, 117246, Moscow, Russian Federation
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Abstract: | Hydrophobic spin labeling of fatty acyl residues at 5-, 12- or 16-positions of phosphatidylcholine liposomes reveals the involvement of surface moieties of bilayer (up to fifth carbon atom of fatty acyl) into interaction with polyadenylic acid: polyuridilic acid duplex and magnesium ions.31P NMR spectra of this system demonstrate participation of nucleotide phosphoryl groups and metal cations in ternary complexation. |
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