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Multinuclear study of RF losses in NaCl/D2O solutions
Authors:X -A Mao  M Holz
Institution:1. Laboratory of Magnetic Resonance, and Atomic and Molecular Physics, Wuhan Institute of Physics, The Chinese Academy of Sciences, P.O. Box 71010, 430071, Wuhan, China
2. Institut für Physikalische Chemie und Elektrochemie der Universit?t Karlsruhe, Germany
Abstract:The RF losses in NMR experiments on ionic solutions have been investigated by multi-NMR. The change of π/2 pulse length (PW)90 for23Na,35Cl,2D,17O and1H nuclei in NaCl/D2O solutions has been systematically studied. Quantitative relation between (PW)90 values and the sample specific conductivity σ has been established. The increase in (PW)90 values has been experimentally correlated to the reduction of the signal-to-noise ratio through17O measurements.
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