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Preparation and Luminescence Properties of the Ternary Europium Complex Incorporated into an Inorganic/Polymer Matrix by a Sol-Gel Method
Authors:Fu  Lianshe  Zhang  Hongjie  Wang  Shubin  Meng  Qingguo  Yang  Kuiyue  Ni  Jianzuan
Affiliation:(1) Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P.R. China
Abstract:Ternary europium complexes with thenoyltrifluoroacetone (TTA) and phenanthroline (phen) were incorporated into SiO2/polymer matrix by a sol-gel method. The gels exhibit the characteristic emission bands of europium ion. In addition, Eu3+ presents a longer fluorescence lifetime in gel than in the corresponding pure complex powder. Concentration effects on the luminescence intensity were investigated. The reasons that are responsible for above results are also discussed in the context.
Keywords:sol-gel method  rare earth complex  hybrid material  luminescence
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