Synthetic studies on sugar-fused erinacines |
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Authors: | Sato Ayato Masuda Tomoya Arimoto Hirokazu Uemura Daisuke |
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Institution: | Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. |
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Abstract: | Samarium-mediated 7-endo-trig radical cyclization afforded excellent stereocontrol of the four contiguous asymmetric centers present in the 6-7-6 tricyclic cores of the (sugar-fused) erinacines E, F, and G. |
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