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Relationships between Allerhand and Schleyer's G scale and other solvent polarity and acidity parameters
Institution:1. State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum, Beijing 102249, PR China;2. School of Petroleum Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, PR China;3. Department of Chemical and Petroleum Engineering, University of Calgary, Calgary, AB T2N 1N4, Canada
Abstract:Values of Allerhand and Schleyer's solvent G parameter for 36 solvents have been correlated with solvent polarity—polarizability properties as well as parameters of solvent acidity. The equations found permit the extension of the G scale to more solvents and quantification of the influence on G of both solvent polarity—polarizability and acidity.
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