Infrarot- und Ramanspektren von Methylsulfonylhydroxylaminen |
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Affiliation: | 1. Graduate Institute of Medical Sciences, College of Medicine, Taipei Medical University, Taipei 110, Taiwan;2. Department of Dermatology, School of Medicine, College of Medicine, Taipei Medical University, Taipei 110, Taiwan;3. Department of Physiology, School of Medicine, College of Medicine, Taipei Medical University, Taipei 110, Taiwan;4. Department of Dermatology, Taipei Medical University-Shuang Ho Hospital, Taipei 110, Taiwan;5. Cancer Research Center, Taipei Medical University Hospital, Taipei 110, Taiwan;1. Department of Anatomy & Embryology, NUTRIM School for Nutrition, Toxicology and Metabolism, Maastricht University, Maastricht, the Netherlands;2. Department of General Surgery, NUTRIM School for Nutrition, Toxicology and Metabolism, Maastricht University, Maastricht, the Netherlands;3. Tytgat Institute for Liver and Gastrointestinal Diseases, Academic Medical Center, University of Amsterdam, Amsterdam, the Netherlands;4. Laboratory Genetic Metabolic Diseases, Academic Medical Center, University of Amsterdam, Amsterdam, the Netherlands;5. Nutrigenomics Consortium, Top Institute of Food and Nutrition, Wageningen, the Netherlands |
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Abstract: | The i.r. and Raman spectra of 12 methylsufonylhydroxylamines and their O-, N- and C- deuterated derivatives were studied.The vibrational assignments were made on the basis of the isotope effects and an approximate normal coordinate analysis of CH3SO2N(H)OH and its deutero-compounds. The SN stretching mode is assigned to a strong band in the region 610–690 cm−1. |
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