Solid state vibrational spectroscopy of disordered crystals. A study of dimethylsulphoxide at 213 K |
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| Affiliation: | 1. U.S. Department of Energy, National Energy Technology Laboratory, 626 Cochrans Mill Road, P.O. Box 10940, Pittsburgh, PA 15236, United States;2. AECOM, Pittsburgh, PA 15236, United States |
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| Abstract: | The vibrational spectrum of crystalline dimethylsulphoxide at 213 K has been studied by i.r. and Raman spectroscopy. Such an experiment is proposed as an example to show how much the dipole-dipole interaction forces can affect the molecular disorder often observed in molecular crystals of compounds containing sulphur atoms. |
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