Vibrational spectroscopic studies on 1,3-dithiacyclohexane and some 2-substituted 1,3-dithia-2-boracyclobexanes |
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| Institution: | 1. I. Physikalisches Institut, Universität zu Köln, Zülpicher Str. 77, 50937 Köln, Germany;2. Department Chemie, Johannes Gutenberg-Universität Mainz, Duesbergweg 10-14, 55128 Mainz, Germany;3. Institut für Physikalische Chemie, Karlsruher Institut für Technologie (KIT), Kaiserstraße 12, 76131 Karlsruhe, Germany;4. Institut für Physikalische Chemie und Elektrochemie, Lehrgebiet A, Leibniz Universität Hannover, Callinstr. 3-3A, 30167 Hannover, Germany;1. Department of Chemistry and Biochemistry & Center for Nanoscience, University of Missouri – St. Louis, Saint Louis, MO 63121, USA;2. Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, IL 62026, USA;1. Institute of Physical Chemistry, RWTH Aachen University, Landoltweg 2, D-52074 Aachen, Germany;2. Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), CNRS UMR 7583, Université Paris-Est Créteil, Université Paris Diderot, 61 avenue du Général de Gaulle, F-94010 Créteil Cedex, France;1. Institute of Physical Chemistry, RWTH Aachen University, Landoltweg 2, D-52074 Aachen, Germany;2. Laboratoire Modélisation et Simulation Multi Echelle, MSME UMR 8208 CNRS, Université Paris-Est, 5 bd. Descartes, F-77454 Marne-la-Vallée, France;3. Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), CNRS UMR 7583, Université Paris-Est Créteil, Université Paris Diderot, 61 avenue du Général de Gaulle, F-94010 Créteil cedex, France;1. Chemical Department, Samara State Technical University, Molodogvardeyskaya str, 224, 443100, Samara, Russian Federation;2. Department of Physical Chemistry, Kazan Federal University, Kremlevskaya str. 18, 420008, Kazan, Russian Federation;3. Department of Physics, Mathematics and Medical Informatics, Tver State Medical University, Sovetskaya 4, 170100, Tver, Russian Federation;4. Department of General Physics, Physics and Technical Faculty, Tver State University, Zhelyabova 33, 170100, Tver, Russian Federation;5. EAHS DCSD 1701 Mountain Industrial Blvd, Stone Mountain, GA 30083, USA |
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| Abstract: | Infrared and Raman spectra are reported for 1,3-dithiacyclohexane and 2-X-1,3-dithia-2-boracyclohexanes, where X = Cl, Br or Ph. Assignments are made in each case assuming a molecular symmetry of Cs. The assignments of ring modes for the dithiaboracyclohexanes are almost all very close to those for the corresponding dithiaboracyclopentanes. |
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