Lanthanide chirality as a tool for assignment of transitions: Tm3+ and Tb3+ pyrogermanates |
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| Affiliation: | 1. Department of Physical Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta 700032, India;2. Department of Chemistry, University of Florida, Gainesville, Florida 32611, U.S.A.;1. Vaccine, Cancer and Immunity Program, Frederick National Laboratory for Cancer Research, Leidos Biomedical Research, Inc., Frederick, MD, USA;2. Department of Laboratory Medicine, Karolinska Institutet, 141 86 Stockholm, Sweden;3. Virus Reference Department, Public Health England, London, UK;4. Chronic Viral Diseases Branch, Division of High-Consequence Pathogens and Pathology, National Center for Emerging and Zoonotic Infectious Diseases, Centers for Disease Control and Prevention, Atlanta, GA, USA;1. State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, PR China;2. College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, PR China;1. The Hong Kong Polytechnic University, Department of Applied Biology and Chemical Technology, State Key Laboratory of Chemical Biology and Drug Discovery, Hung Hom, Kowloon, Hong Kong SAR, China;2. The Hong Kong Polytechnic University, Shenzhen Research Institute, Shenzhen, China;1. School of Agriculture, Ningxia University, Yinchuan, Ningxia 750021, PR China;2. State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau, College of Natural Resources and Environment, Northwest A & F University, Yangling, Shaanxi 712100, China;3. Institute of Soil and Water Conservation, Chinese Academy of Sciences and Ministry of Water Resource, Yangling, Shaanxi 712100, China;4. CAS Center for Excellence in Quaternary Science and Global Change, Xi''an 710061, China;5. Team Soil, Water and Land Use, Wageningen Environmental Research. Droevendaalsesteeg 3, Wageningen 6708RC, Netherlands;1. School of Public Health and Social Work and Institute of Health and Biomedical Innovation, Faculty of Health, Queensland University of Technology, Brisbane, Australia;2. International Laboratory for Air Quality and Health, Queensland University of Technology, Brisbane, Australia;3. School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham B15 2TT, United Kingdom;4. The University of Queensland, National Research Centre for Environmental Toxicology, Brisbane, Australia;5. Centre for Air Quality and Health Research and Evaluation, 431 Glebe Point Road, Glebe, Australia;6. School of Clinical Sciences and Institute of Health and Biomedical Innovation, Faculty of Health, Queensland University of Technology, Brisbane, Australia |
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| Abstract: | Although chiral studies have proven to be useful in the assignment of transitions in biological molecules, organic molecules and transition metal complexes, their potential for lanthanide transitions needs to be demonstrated. This paper explores the usefulness of circular dichroism (CD) studies in the assignment of lanthanide Δ J = 0, ± 1 transitions with two chiral single crystals, Tm2Ge2O7 (Tm-PG) and Tb2Ge2O7 (Tb-PG). |
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