Study of the reaction of fluoroalkyl β-ketoesters with methylhydrazine by1H and19F NMR spectroscopy |
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Authors: | V. I. Saloutin M. I. Kodess A. N. Fomin S. I. Selivanov B. A. Ershov K. I. Pashkevich |
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Affiliation: | (1) Institute of Chemistry, Ural Branch, Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions By1H and19F NMR spectroscopy it was shown that reaction of fluoroalkyl -ketoesters with methylhydrazine in deuteromethanol at –30 to 30C involves intermediate formation of the -ketoester salts with methylhydrazine and 3,5-dioxypyrazolidines which successively split off methanol and H2O with formation of 3-oxypyrazolines and pyrazol-5-ones, respectively.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 399–402, February, 1988. |
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