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2H NMR of Deuterofullerites C60D x |
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| Authors: | V. P. Tarasov Yu. B. Muravlev V. N. Fokin Yu. M Shul'ga |
| Affiliation: | (1) Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia;(2) Institute for the Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, 142432, Russia |
| Abstract: | Deuterofullerites C60Dx have been studied by means of 2H NMR spectroscopy. It has been established that there are two types of carbon–deuterium bindings in the samples under study: tip C–D with quadrupole constant coupling (QCC) 171 kHz and bridge –C...D...C– with QCC 56 kHz. It is possible that the latter bond is a result of the rigidity of the lattice, which is unusual for fullerene compounds. |
| Keywords: | fullerenes deuterofullerenes 2H NMR spectroscopy |
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